Processes and apparatuses for formation, separation, pelletizing storage and re-gasification of gas hydrate

Document Type : Review Article

Authors

1 Department of Chemical Engineering, Semnan University

2 Semnan University, Department of Chemical Engineering

Abstract

In recent years, the feasibility of utilizing gas hydrates in industrial systems draws much attention as a subject of engineering studies. Despite the suggested applications for gas hydrate in transportation and storage of natural gas, desalination of water, etc., there have been few applied industrial experiences with gas hydrates. There are several patents and papers on promotion of gas hydrate formation thermodynamics and kinetics , but apparatuses and processes are rarely discussed.  In designing a process based on gas hydrate for industrial application, one must include the following operations: formation, separation, pelletizing, storage, transportation and re-gasification. In this review article, different operations considering applications of gas hydrate are fully discussed. These operations are classified based on both contact of liquid and vapour phases and methods of conducting mass and heat transfer.

Keywords

Main Subjects


[1]     loan, E. Dendy, "Fundamental principles and applications of natural gas hydrates," Nature, 426(6964), (2003) pp. 353-363.
[2]     Khodaverdiloo, Khadijeh Rostami, Amir Erfani, Kiana Peyvandi, and Farshad Varaminian. "Synergetic effects of polyacrylamide and nonionic surfactants on preventing gas hydrate formation." Journal of Natural Gas Science and Engineering 30 (2016): 343-349.
[3]     Hao W, Wang J, Fan S, Hao W., "Evaluation and analysis method for natural gas hydrate storage and transportation processes," Energy conversion and management, 49(10), (2008) pp. 2546-2553.
[4]     Gudmundsson JS, Parlaktuna M, Khokhar A, "Storage of natural gas as frozen hydrate," SPE Production & Facilities 9(1), (1994) pp. 69-73.
[5]     Javanmardi, J., and M. Moshfeghian, "Energy consumption and economic evaluation of water desalination by hydrate phenomenon," Applied thermal engineering 23 (7), (2003) pp.  845-857.
[6]     ark, Kyeong-nam, Sang Yeon Hong, Jin Woo Lee, Kyung Chan Kang, Young Cheol Lee, Myung-Gyu Ha, and Ju Dong Lee, "A new apparatus for seawater desalination by gas hydrate process and removal characteristics of dissolved minerals (Na+, Mg2+, Ca2+, K+, B3+)," Desalination, 274 (1),  (2011) pp. 91-96.
[7]     Nagata T, Tajima H, Yamasaki A, Kiyono F, Abe Y, "An analysis of gas separation processes of HFC-134a from gaseous mixtures with nitrogen—Comparison of two types of gas separation methods, liquefaction and hydrate-based methods, in terms of the equilibrium recovery ratio," Separation and Purification Technology, 64(3), (2009) pp. 351-356.
[8]     Eslamimanesh A, Mohammadi AH, Richon D, Naidoo P, Ramjugernath D, "Application of gas hydrate formation in separation processes: A review of experimental studies," The Journal of Chemical Thermodynamics, 46(1), (2012) pp. 62-71.
[9]     Erfani, Amir, Saeed Taghizadeh, Maryam Karamoddin, and Farshad Varaminian. "Experimental and computational study on clathrate hydrate of tetrahydrofuran formation on a subcooled cylinder." International Journal of Refrigeration 59 (2015): 84-90.
[10]  Javanmardi J, Nasrifar K, Najibi SH, Moshfeghian M, "Economic evaluation of natural gas hydrate as an alternative for natural gas transportation," Applied Thermal Engineering, 25(11), (2005) pp. 1708-1723.
[11]  Gudmundsson J, Hveding F, Borrehaug A, editors, "Transport of natural gas as frozen hydrate." Proc. 5th Intern. Offshore and Polar Engineering Conference, Hague Netherlands, (1995).
[12]  [12] BALCZEWSKI JT, U.S. patent, "APPARATUS FOR CONTINUOUS PRODUCTION OF HYDRATES", (2008).
[13]  [13] Gudmundsson JS, U.S. patent, "Method for production of gas hydrates for transportation and storage", (1996).
[14]  [14] Heinemann RF, Huang DDT, Long J, Saeger RB, U.S. patent, "Process for making gas hydrates", (2000).
[15]  Heinemann RF, Huang DDT, Long J, Saeger RB, U.S. patent, "Method for producing gas hydrates utilizing a fluidized bed", (2001).
[16]  Hester KC, Howard JJ, U.S patent, "SELECTIVE HYDRATE PRODUCTION WITH CO2 AND CONTROLLED DEPRESSURIZATION",(2011).
[17]  HIRAIDE M, SERIZAWA K, NAKAMURA K, NAKAOKA M., U.S patent, "METHOD OF PRODUCING GAS HYDRATE", (2008).
[18]  IWASAKI T, TAKAHASHI M, U.S. patent,"PROCESS FOR PRODUCTION OF GAS HYDRATE", (2007).
[19]  Iwasaki T, Takahashi M, Arai T, Takahashi S, Takamoto K, Ogawa K, et al., U.S. patent, "PROCESS AND APPARATUS FOR PRODUCING GAS HYDRATE PELLET", (2012).
[20]  KATOH Y, NAGAMORI S, IWASAKI T, ARAI T, HORIGUCHI K, MURAYAMA T, et al., U.S patent, "GAS HYDRATE PRODUCTION APPARATUS AND DEWATERING UNIT", (2007).
[21]  KIMURA T, IWASAKI S, ITOH K, UEHARA S, YOSHIKAWA K, NAGAYASU H, et al., U.S. patent, "GAS HYDRATE PRODUCTION DEVICE AND GAS HYDRATE DEHYDRATING DEVICE", (2005).
[22]  Lee JD, Kim HJ, Kim SR, Hong SY, Park HO, Ha MK, et al., U.S. patent, "APPARATUS AND METHOD FOR CONTINUOUSLY PRODUCING AND PELLETIZING GAS HYDRATES USING DUAL CYLINDER", (2010).
[23]  Lee JD, Lee JW, Kang KC, Park KN, Ha MK, Jeon SK, et al., U.S. patent, "DEVICE AND METHOD FOR CONTINUOUS HYDRATE PRODUCTION AND DEHYDRATION BY CENTRIFUGAL FORCE", (2010).
[24]  Matsuo K, Kurosaka S, Yanagimori Y, Asano S, Shinoda J, U.S. patent, "Device and method for extracting a gas hydrate", (2004).
[25]  NAGAMORI S, MURAYAMA T, MORIYA H, ARAI T, OYA N, U.S. patent, "GAS HYDRATE PRODUCTION APPARATUS", (2009).
[26]  Spencer DF, North WJ, U.S. patent, "Method for the production of carbon dioxide hydrates", (1996).
[27]  WATANABE K, SUGANOYA K, YOSHIDA T, OGAWA K, NANBARA S, IMAI S, U.S patent, "Gas hydrate compression molding machine", (2008).
[28]  WATANABE S, IMAI S, SHINAGAWA K, U.S. patent, "APPARATUS AND METHOD FOR GASIFYING GAS HYDRATE PELLET", (2009).
[29]  Wilson JC, U.S patent, "Method and apparatus for rapid and continuous hydration of polymer-based fracturing fluids", (1991).
[30]  Yoshikawa K, Kondo Y, Kimura T, Fujimoto T, U.S. patent, "Production method for hydrate and device for proceeding the same", (2003).
[31]  Bi Y, Guo T, Zhu T, Zhang L, Chen L,  "Influences of additives on the gas hydrate cool storage process in a new gas hydrate cool storage system," Energy conversion and management, 47(18), (2006) pp. 2974-2982.
[32]  Di Profio P, Arca S, Germani R, Savelli G, "Surfactant promoting effects on clathrate hydrate formation: Are micelles really involved?," Chemical engineering science, 60(15), (2005) pp. 4141-4145.
[33]  Jones AG., "Crystallization process systems", Butterworth-Heinemann, (2002).
[34]  Kashchiev Dimo, and Abbas Firoozabadi, " Induction time in crystallization of gas hydrates," Journal of crystal growth, 250(3), (2003) pp. 499-515.
[35]  Guo, Z., A. G. Jones, and N. Li, "The effect of ultrasound on the homogeneous nucleation of BaSO4 during reactive crystallization," Chemical Engineering Science, 61(5), (2006) pp. 1617-1626.
[36]  Park, Sung-Seek, and Nam-Jin Kim, "Study on methane hydrate formation using ultrasonic waves," Journal of Industrial and Engineering Chemistry, 19(5), (2013) pp. 1668-1672.
[37]  Xie Y, Guo K, Liang D, Fan S, Gu J., "Steady gas hydrate growth along vertical heat transfer tube without stirring," Chemical engineering science, 60(3), (2005) pp. 777-786.
[38]  Linga P, Kumar R, Lee JD, Ripmeester J, Englezos P., "A new apparatus to enhance the rate of gas hydrate formation: Application to capture of carbon dioxide," International Journal of Greenhouse Gas Control, 4(4), (2010) pp.  630-637.
[39]  Brown, Thomas D., Charles E. Taylor, and Mark P. Bernardo, "Rapid Gas Hydrate Formation Processes: Will They Work?," Energies, 3(6), (2010) pp. 1154-1175.
[40]  Song KY, Feneyrou G, Fleyfel F, Martin R, Lievois J, Kobayashi R., "Solubility measurements of methane and ethane in water at and near hydrate conditions," Fluid phase equilibria, 128(1), (1997) pp. 249-259.
[41]  Chapoy A, Mohammadi AH, Richon D, Tohidi B., "Gas solubility measurement and modeling for methane–water and methane–ethane–n-butane–water systems at low temperature conditions,", Fluid phase equilibria, 220(1), (2004) pp. 111-119.
[42]  Hashemi, Shahrzad, Arturo Macchi, and Phillip Servio, "Gas–liquid mass transfer in a slurry bubble column operated at gas hydrate forming conditions,"Chemical engineering science, 64(16), (2009) pp. 3709-3716.
[43]  Matsuda, Sadatoshi, Hidehiko Tsuda, and Yasuhiko H. Mori, "Hydrate formation using water spraying onto a cooled solid surface in a guest gas," AIChE journal, 52(8), (2006) pp. 2978-2987.
[44]  Fujita, Shinya, Kuniyoshi Watanabe, and Yasuhiko H. Mori, "Clathrate‐hydrate formation by water spraying onto a porous metal plate exuding a hydrophobic liquid coolant," AIChE journal, 55(4), (2009) pp. 1056-1064.
[45]  Mori, Yasuhiko H., and Takaaki Mochizuki, "Mass transport across clathrate hydrate films—a capillary permeation model," Chemical Engineering Science, 52(20), (1997) pp. 3613-3616.
[46]  Kobayashi I, Ito Y, Mori YH.,  "Microscopic observations of clathrate-hydrate films formed at liquid/liquid interfaces. I. Morphology of hydrate films," Chemical engineering science, 56(14), (2001) pp. 4331-4338.
[47]  Luo YT, Zhu JH, Fan SS, Chen GJ., "Study on the kinetics of hydrate formation in a bubble column," Chemical engineering science, 62(4), (2007) pp.1000-1009.
[48]  Luo Y, Zhu J, Chen G., "Numerical Simulation of Separating Gas Mixtures via Hydrate Formation in Bubble Column,", Chinese Journal of Chemical Engineering, 15(3), (2007) pp. 345-352.
[49]  Takahashi M, Kawamura T, Yamamoto Y, Ohnari H, Himuro S, Shakutsui H., "Effect of shrinking microbubble on gas hydrate formation," The Journal of Physical Chemistry B, 107(10), (2003) pp. 2171-2173.
[50]  Terasaka K, Hirabayashi A, Nishino T, Fujioka S, Kobayashi D., " Development of microbubble aerator for waste water treatment using aerobic activated sludge," Chemical engineering science, 66(14) (2011) pp. 3172-3179.
[51]  Ohnari H., "Swirling type micro-bubble generating system", U.S. Patents, (2009).
[52]  Semmens MJ, Gantzer CJ, Bonnette MJ., "High efficiency micro bubble aeration", U.S. Patents, (1997).
[53]  Murayama T, Iwabuchi W, Ito M, Takahashi M. "Effects of guest gas on pelletizing performance of natural gas hydrate (NGH) pellets," Proceedings of the 7th International Conference on Gas Hydrates, ( 2011).
[54]  Yamamoto, Yoshitaka, et al. "FORMATION OF GAS HYDRATE UNDER LOW TEMPERATURE AND LOW PRESSURE USING ULTRASONIC MIST GENERATOR." Proceedings of the 7th International Conference on Gas Hydrates, (2011).
[55]  Takeya S, Uchida T, Nagao J, Ohmura R, Shimada W, Kamata Y, et al., "Particle size effect of CH4 hydrate for self-preservation,"Chemical engineering science, 60(5), (2005) pp. 1383-1387.
[56]  Katoh Y, Horiguchi K, Iwasaki T, Nagamori S, U.S. patent, "Process for producing gas hydrate pellet", (2011).
[57]  Watanabe, S., Takahashi, S., Mizubayashi, H., Murata, S. Murakami, "A demonstration project of NGH land transportation system," Proceedings of the Sixth International Conference on Gas Hydrates, Vancouver, Canada, (2008).
[58]  Rajnauth, Jerome,  Maria Barrufet, "Monetizing Gas: Focusing on Developments in Gas Hydrate as a Mode of Transportation," Energy Science and Technology,  4(2), (2012) pp. 61-68.
[59]  [59] H. Kanda, "Economic study on natural gas transportation with natural gas hydrate (NGH) pellets." 23rd world gas conference, Amsterdam, (2006).
[60]  Naredi, P., Narkiewicz, M., Strohm, T., Suriyapraphadilok, U., Wang, B., & Zhang, "Optimal recovery of methane hydrates of the hydrate ridge, offshore Oregon," College of Earth and Mineral Science (Pennstate) Report FSc 503, (2004).
[61]  Gudmundsson, J. S., A. Borrehaug. "Frozen hydrate for transport of natural gas," Proceedings of 2nd International Conference on Gas Hydrate, Toulouse, France, (1996).