Synthesis of TiO2 Nanoparticles and Investigation of Heat Transfer and Exergetic Performance of a Shell and Tube Heat Exchanger with TiO2-PGW Nanofluid

Document Type : Full Length Research Article

Authors

Department of Mechanical Engineering, Chittagong University of Engineering and Technology, Chattogram- 4349, Bangladesh

Abstract

In this experimental study, titanium dioxide (TiO₂) nanoparticles were synthesized using an ultrasound-assisted technique. The structural as well as morphological characteristics of the produced TiO₂ nanoparticles were studied through X-ray diffraction (XRD) and scanning electron microscopy (SEM). Heat transfer, as well as exergetic parameters of propylene glycol-water (PGW)-based TiO₂ nanofluid in a shell-and-tube heat exchanger, were then explored. The nanofluid was made ready by mixing 60% water and 40% propylene glycol, incorporating TiO₂ nanoparticle concentrations of 0.1 vol.%, 0.2 vol.%, and 0.3 vol.% through a two-step process. The flow rate of the nanofluid was varied between 6–12 l/min, while the flow rate of the hot water was maintained at 12 l/min. The study revealed that increasing both the flow rate and nanoparticle concentration of the nanofluid significantly improved the heat transfer rate ( ) as well as the overall heat transfer coefficient (U). Specifically, at a nanoparticle concentration of 0.3 vol.% and a flow rate of 12 l/min, the heat transfer rate increased by 44.3%, and the heat transfer coefficient increased by 46.1%. Furthermore, the average effectiveness of the heat exchanger improved with nanoparticle concentrations of 0.1 vol.%, 0.2 vol.%, and 0.3 vol.%, showing increases of 11.91%, 29.88%, and 41.82%, respectively. The research also indicated that exergy loss as well as the dimensionless exergy loss initially increased with higher nanoparticle concentrations but then decreased as the concentration continued to rise. Notably, at a concentration of 0.3 vol.% and a nanofluid flow rate of 6 l/min, the highest exergetic sustainability index (0.44) and the lowest environmental impact factor (2.3) were observed.

Keywords

Main Subjects


[1]   Mukherjee, S., Poloju, V. and Mishra, P.C., 2023. Heat transfer, exergoeconomic performance and sustainability impact of a novel CuO+ MgO+ GO/Water ternary nanofluid. Applied Thermal Engineering235, 121391. https://doi.org/10.1016/j.applthermaleng.2023.121391
[2]   Wang, B., Klemeš, J.J., Li, N., Zeng, M., Varbanov, P. S. and Liang, Y., 2021. Heat exchanger network retrofit with heat exchanger and material type selection: A review and a novel method. Renewable and Sustainable Energy Reviews138, 110479. https://doi.org/10.1016/j.rser.2020.110479
[3]   Das, U.D., Hossain, M.A.M., Ahamed, J.U. and Razzaq, M.E.A., 2022. Heat transfer and exergy analysis of a shell and tube heat exchanger using PGW based ZnO nanofluids. International Journal of Automotive and Mechanical Engineering, 19(2), pp. 9773-9789. https://doi.org/10.15282/ijame.19.2.2022.12.0754
[4]   Dhar, G., Raha, H.A., Razzaq, M.A. and Ahamed, J.U., 2019. Thermal Performance Improvement of a NFU Type Heat Exchanger Using Hybrid Nanofluids. International Conference on Mechanical, Industrial and Materials Engineering 2019 (ICMIME2019) 17-19 December, 2019, RUET, Rajshahi, Bangladesh.
[5]   Etghani, M.M. and Baboli, S.A.H., 2017. Numerical investigation and optimization of heat transfer and exergy loss in shell and helical tube heat exchanger. Applied Thermal Engineering, 121, pp. 294–301. https://doi.org/10.1016/j.applthermaleng.2017.04.074
[6]   Shahrul, I.M., Mahbubul, I.M., Saidur, R., Khaleduzzaman, S.S., Sabri, M.F.M. and Rahman, M.M., 2014. Effectiveness study of a shell and tube heat exchanger operated with nanofluids at different mass flow rates. Numerical Heat Transfer; Part A: Applications, 65(7), pp. 699–713. https://doi.org/10.1080/10407782.2013.846196
[7]   Dhar, G., Razzaq, M.A., Ahamed, J.U. and Chakaraborty, P., 2020. Experimental Analysis for the Enhancement of Heat Transfer in a Tube Using Double Counter Twisted Tape. 5th International Conference on Mechanical Engineering and Renewable Energy 2019 (ICMERE2019) 11–13 December, 2019, Chittagong, Bangladesh.
[8]   Aghayari, R., Maddah, H., Zarei, M., Dehghani, M. and Kaskari Mahalle, S.G., 2014. Heat transfer of nanofluid in a double pipe heat exchanger. International Scholarly Research Notices, 2014(1), 736424. https://doi.org/10.1155/2014/736424
[9]   Eneren, P., Aksoy, Y.T. and Vetrano, M.R., 2023. Practical challenges in nanofluid convective heat transfer inside silicon microchannels. Energies, 16(23), 7885. https://doi.org/10.3390/en16237885
[10] Wang, S., Wen, J. and Li, Y., 2008. An experimental investigation of heat transfer enhancement for a shell-and-tube heat exchanger. Applied Thermal Engineering, 29(11–12), pp. 2433–2438.  https://doi.org/10.1016/j.applthermaleng.2008.12.008
[11] Devireddy, S., Mekala, C.S.R. and Veeredhi, V.R., 2016. Improving the cooling performance of automobile radiator with ethylene glycol water based TiO2 nanofluids. International Communications in Heat and Mass Transfer, 78, pp. 121–126. https://doi.org/10.1016/j.icheatmasstransfer.2016.09.002
[12] Duong, N.T., Vuong, L.D., Son, N.M., Tuyen, H. van and Chuong, T. van, 2017. The synthesis of TiO2 nanoparticles using sulfuric acid method with the aid of ultrasound. Nanomaterials and Energy, 6(2), pp. 82–88. https://doi.org/10.1680/jnaen.17.00009
[13] Sekrani, G. and Poncet, S., 2018. Ethylene- and propylene-glycol based nanofluids: A litterature review on their thermophysical properties and thermal performances. Applied Sciences, 8(11), 2311. https://doi.org/10.3390/app8112311
[14] Buschmann, M. H., Azizian, R., Kempe, T., Juliá, J. E., Martínez-Cuenca, R., Sundén, B. and Ala-Nissila, T., 2018. Correct interpretation of nanofluid convective heat transfer. International Journal of Thermal Sciences129, pp. 504-531. https://doi.org/10.1016/j.ijthermalsci.2017.11.003
[15] Aksoy, Y.T., Enayati, F., Eneren, P. and Vetrano, M.R., 2025. Experimental study on enhanced heat transfer via nanoparticle depositions using TiO2-water nanofluid sprays. Applied Thermal Engineering, 264, 125450. https://doi.org/10.1016/j.applthermaleng.2025.125450
[16] Hamilton, R.L., 1962. Thermal conductivity of heterogeneous two-component systems. Industrial and Engineering Chemistry Fundamentals, 1(3), pp. 187–191. https://doi.org/10.1021/i160003a005
[17] Choi, S.U.S. 1995. Enhancing thermal conductivity of fluids with nanoparticles. In: Siginer DA, Wang HP, Eds., Developments and Applications of Non-Newtonian Flows, 66, pp. 99-105. https://www.osti.gov/servlets/purl/196525.
[18] Li, S., Eastman, J.A., Choi, U.S., Thompson, L.J. and Lee, S., 2011. Enhanced thermal conductivity through the development of nanofluids. MRS Proceedings, 457, pp. 3–11. https://doi.org/10.1557/PROC-457-3
[19] Masuda, H., Ebata, A., Teramae, K. and Hishinuma N., 1993. Alteration of thermal conductivity and viscosity of liquid by dispersing ultra-fine particles. dispersion of Al2O3, SiO2, and TiO2 ultra-fine particles. Netsu Bussei, 7(4), pp. 227–233.
[20] Cabaleiro, D., Nimo, J., Pastoriza-Gallego, M.J., Piñeiro, M.M., Legido, J.L. and Lugo, L., 2015. Thermal conductivity of dry anatase and rutile nano-powders and ethylene and propylene glycol-based TiO2 nanofluids. Journal of Chemical Thermodynamics, 83, pp. 67–76. https://doi.org/10.1016/j.jct.2014.12.001
[21] Sundar, L.S., Ramana, E.V., Singh, M.K., Gracio, J. and A. Sousa, C.M., 2014. Preparation, thermal and rheological properties of propylene glycol and water mixture based Fe3O4 nanofluids. Journal of Nanofluids, 3(3), pp. 200–209. https://doi.org/10.1166/jon.2014.1108
[22] Hussein, A.M., Bakar, R.A., Kadirgama, K. and Sharma, K.V. 2014. Heat transfer augmentation of a car radiator using nanofluids. Heat and Mass Transfer, 50(11), pp. 1553–1561. https://doi.org/10.1007/s00231-014-1369-2
[23] Palanisamy, K. and Kumar, P.C.M., 2019. Experimental investigation on convective heat transfer and pressure drop of cone helically coiled tube heat exchanger using carbon nanotubes/water nanofluids. Heliyon, 5(5), e01705. https://doi.org/10.1016/j.heliyon.2019.e01705
[24] Jagadishwar, K. and Babu, S.S., 2017. Performance Investigation of Water and propylene glycol mixture based nano-fluids on automotive radiator for enhancement of heat transfer. International Journal of Mechanical Engineering and Technology, 8(7), pp. 822–833.
[25] Mohammadzadeh, A.M., Jafari, B. and Hosseinzadeh, K., 2025. Performance enhancement of disc-and-doughnut shell and tube heat exchangers through various tube layouts and ternary nanoparticle integration. Applied Thermal Engineering, 265, 125515. https://doi.org/10.1016/j.applthermaleng.2025.125515
[26] Mohammadzadeh, A.M., Jafari, B., Hosseinzadeh, K. and Paikar, E., 2025. Numerical investigation of segmental baffle design in shell and tube heat exchangers with varying inclination angles and spacing. Scientific Reports15(1), 4683. https://doi.org/10.1038/s41598-025-87652-x
[27] Khedher, N.B., Hosseinzadeh, K., Abed, A.M., Khosravi, K., Mahdi, J.M., Sultan, H.S. and Talebizadehsardari, P., 2024. Accelerated charging of PCM in coil heat exchangers via central return tube and inlet positioning: A 3D analysis. International Communications in Heat and Mass Transfer, 152, 107275. https://doi.org/10.1016/j.icheatmasstransfer.2024.107275
[28] Paikar, M., Hosseinzadeh, K., Kermani, J.R. and Ganji, D.D., 2024. Hydrothermal assessment of a double-pass shell and tube heat exchanger in the presence of blade turbulators with different configurations. International Journal of Thermofluids, 21, 100577. https://doi.org/10.1016/j.ijft.2024.100577
[29] Moghaddam, M.E., Abandani, M.H.S., Hosseinzadeh, K., Shafii, M.B. and Ganji, D.D., 2022. Metal foam and fin implementation into a triple concentric tube heat exchanger over melting evolution. Theoretical and Applied Mechanics Letters, 12(2), 100332. https://doi.org/10.1016/j.taml.2022.100332
[30] Mohammadzadeh, A.M., Jafari, B. and Hosseinzadeh, K., 2024. Comprehensive numerical investigation of the effect of various baffle design and baffle spacing on a shell and tube heat exchanger. Applied Thermal Engineering, 249, 123305. https://doi.org/10.1016/j.applthermaleng.2024.123305
[31] Ahamed, J.U., Saidur, R., Masjuki, H.H., Mekhilef, S., Ali, M.B. and Furqon, M.H., 2011. An application of energy and exergy analysis in agricultural sector of Malaysia. Energy Policy, 39, pp. 7922–7929. https://doi.org/10.1016/j.enpol.2011.09.045
[32] Hossain, S., Chowdhury, H., Chowdhury, T., Ahamed, J.U., Saidur, R., Sait, S.M. and Rosen, M.A., 2020. Energy, exergy and sustainability analyses of Bangladesh’s power generation sector. Energy Reports, 6, pp. 868-878. https://doi.org/10.1016/j.egyr.2020.04.010
[33] Gupta, S.K., Verma, H. and Yadav, N., 2022. A review on recent development of nanofluid utilization in shell & tube heat exchanger for saving of energy. Materials Today: Proceedings, 54, pp. 579-589. https://doi.org/10.1016/j.matpr.2021.09.455
[34] Razzaq, M.A., Ahamed J.U. and  Hossain, M.A.M., 2020. Effect of TiO2/MO nano-lubricant on energy and exergy savings of an air conditioner using blends of R22/R600a. International Journal of Automotive and Mechanical Engineering, 17(4), pp. 8283–8297. https://doi.org/10.15282/ijame.17.4.2020.06.0626
[35] Prajapati, P., Raja, B.D., Savaliya, H., Patel, V. and Jouhara, H., 2024. Thermodynamic evaluation of shell and tube heat exchanger through advanced exergy analysis. Energy, 292, 130421. https://doi.org/10.1016/j.energy.2024.130421
[36] Romero, J.C. and Linares, P., 2014. Exergy as a global energy sustainability indicator. A review of the state of the art. Renewable and Sustainable Energy Reviews, 33, 427–442. https://doi.org/10.1016/j.rser.2014.02.012
[37] Durmuş, A., 2004. Heat transfer and exergy loss in cut out conical turbulators. Energy Conversion and Management, 45(5), pp. 785–796. https://doi.org/10.1016/S0196-8904(03)00186-9
[38] Dizaji, H.S., Khalilarya, S., Jafarmadar, S., Hashemian, M. and Khezri, M., 2016. A comprehensive second law analysis for tube-in-tube helically coiled heat exchangers. Experimental Thermal and Fluid Science, 76, pp. 118–125. https://doi.org/10.1016/j.expthermflusci.2016.03.012
[39] Khairul, M.A., Alim, M.A., Mahbubul, I.M., Saidur, R., Hepbasli, A. and Hossain, A., 2014. Heat transfer performance and exergy analyses of a corrugated plate heat exchanger using metal oxide nanofluids. International Communications in Heat and Mass Transfer, 50, 8–14. https://doi.org/10.1016/j.icheatmasstransfer.2013.11.006
[40] Esfahani, M.R. and Languri, E.M., 2017. Exergy analysis of a shell-and-tube heat exchanger using graphene oxide nanofluids. Experimental Thermal and Fluid Science, 83, pp. 100-106. https://doi.org/10.1016/j.expthermflusci.2016.12.004
[41] Pak, B.C. and Cho, Y.I., 1998. Hydrodynamic and heat transfer study of dispersed fluids with submicron metallic oxide particles. Experimental Heat Transfer, 11(2), pp. 151–170. https://doi.org/10.1080/08916159808946559
[42] Smyth, J.R. and Bish, D.L., 1988. Crystal structures and cation sites of the rockforming mineral. First Edition. Boston, Allen and Unwin.
[43] Torres, P. and Rurali, R., 2019. Thermal conductivity of rutile and anatase TiO2 from First-Principles. Journal of Physical Chemistry C, 123(51), pp. 30851–30855. https://doi.org/10.1021/acs.jpcc.9b09299
[44] Smith, S.J., Stevens, R., Liu, S., Li G., Navrotsky, A., Boerio-Goates, J. and Woodfield, B.F., 2009. Heat capacities and thermodynamic functions of TiO2 anatase and rutile: Analysis of phase stability. American Mineralogist, 94(2–3), pp. 236–243. https://doi.org/10.2138/am.2009.3050
[45] Hussein, A.M., Bakar, R.A., Kadirgama, K. and Sharma, K.V., 2013. Experimental measurement of nanofluids thermal properties. International Journal of Automotive and Mechanical Engineering, 7(June), pp. 850–863. http://dx.doi.org/10.15282/ijame.7.2012.5.0070
[46] Propylene Glycol based Heat-Transfer Fluids, The Engineering ToolBox, Mar.30, 2020. [Online]. Available: https://www.engineeringtoolbox.com/propylene-glycol-d_363.html.
[47] Holman, J.P., 2010. Heat Transfer: Tenth Edition, New York, The McGraw-Hill companies, Inc.
[48] Arslan, E. and Aktas, M., 2020. 4E analysis of infrared-convective dryer powered solar photovoltaic thermal collector. Solar Energy, 208, pp. 46–57. https://doi.org/10.1016/j.solener.2020.07.071
[49] Gojak, M. and Bajc, T., 2019. Thermodynamic sustainability assessment for heating of residential building. E3S Web of Conferences 111 CLIMA 2019, 04028.
[50] Pratheepa, M.I. and Lawrence, M., 2017. X-Ray diffraction analyses of titanium dioxide nanoparticles. International Journal of Scientific Research in Science and Technology, 3(11), pp. 83-88.
[51] Theivasanthi, T. and Alagar, M., 2013. Titanium dioxide (TiO2) nanoparticles XRD analyses: An insight. arXiv preprint arXiv:1307.1091. https://doi.org/10.48550/arXiv.1307.1091
[52] Hanaor, D., Sorrell, C., Hanaor, D.A.H. and Sorrell, C.C., 2011. Review of the anatase to rutile phase transformation. Journal of Materials Science, 46(4), pp. 855-874.  https://doi.org/10.1007/s10853-010-5113-0